Polycyclic aromatic hydrocarbons and their molecular diagnostic ratios in urban atmospheric respirable particulate matter   总被引：2，自引：5，他引：2  

María del Rosario Sienra  Nelson G. Rosazza  Margarita Prndez 《Atmospheric Research》2005,75(4):267-281

Atmospheric concentrations of polycyclic aromatic hydrocarbons (PAHs) in Santiago de Chile city were evaluated to study particulate PAHs profiles during cold and spring weather periods. Urban atmospheric particulate matter PM10 was collected using High Volume PM10 samplers. Fifteen samples of 24 h during austral winter and 20 samples of 24 h during spring, 2000 were collected at two sampling sites (North–East and Central areas of the city) whose characteristics were representative of the prevailing conditions. Seventeen PAHs were quantified and total PAHs concentration ranged from 1.39 to 59.98 ng m⁻³, with a seasonal variation (winter vs. spring ratio) from 0.5 to 12.6 ng m⁻³. Molecular diagnostic ratios were used to characterize and identify PAHs emission sources such as combustion and biogenic emissions. Results showed that the major sources of respirable organic aerosol PM10 in Santiago are mobile and stationary ones.  相似文献   

Factors affecting arsenic concentration in groundwaters from Northwestern Chaco-Pampean Plain,Argentina     

María Gabriela García  Ondra Sracek  Diego Sebastián Fernández  Margarita del Valle Hidalgo 《Environmental Geology》2007,52(7):1261-1275

The concentration of arsenic measured in groundwater from three aquifers in the study area located in the Eastern Tucuman province, Argentina, mostly depends on the lithology, but the spatial and temporal variations of concentrations seem to be also controlled by pH changes, climatic factors, and human perturbations. The highest concentrations of As (more than 1,000 μg L⁻¹) were found in the shallow aquifer, made of As-rich loess, while the lowest concentrations were measured in the deep confined aquifer, consisting of alternating layers of alluvial sands/gravels and clays. Intermediate values were measured in the semiconfined aquifer made of the fluvial sediments deposited in the Salí River valley, that alternate in the upper part of the sedimentary sequence with layers of loess. Because most of As in the loess is considered to be adsorbed onto Fe-oxyhydroxide coatings, the increase of pH in the flow direction (west-east) leads to increasing arsenic concentrations towards the eastern border of the study area. The decomposition of organic wastes poured into the Salí River or associated with local and diffuse sources of contamination in the eastern part of the study area depletes dissolved oxygen, which leads to the reductive dissolution of Fe and Mn oxyhydroxides, and to the subsequent release of the adsorbed and co-precipitated As. This process mainly affects shallow groundwater and the upper part of the semiconfined aquifer. Geochemical and hydrological data also suggest that rising water table levels at the end of the wet season may also lead to reductive dissolution of As-rich Fe oxyhydroxides in the shallow aquifer.  相似文献   

Chemical behavior of the Salí River, Province of Tucumán, Argentina     

M. Galindo  M. Vece  M. Perondi  M. Monserrat Aráoz  G. García  M. del V. Hidalgo  M. Apella  M. Blesa 《Environmental Geology》2001,40(7):847-852

Major ionic composition and other chemical parameters were determined at five sampling stations on the Salí River (Province of Tucumán, Argentina). The heavy human usage of the river causes increased levels of dissolved ions, from the dissolution of halite and gypsum, and from the weathering of basic sediments. Correlations demonstrate that sodium chloride and sulphate, and calcium carbonate are the main contributors to dissolved ions in the river. In the polluted region, south of the Celestino Gelsi dam, the main source of calcium and sulphate is the dissolution of gypsum. Large amounts of halite are also dissolved. Weathering of biotite, K-feldspar and albite are suggested by the data. Conductivity, dissolved oxygen and organic matter all indicate severe contamination by organic matter (mainly from sugar-cane processing) in the lower course. The data also demonstrate a substantial improvement in water quality before the discharge of the river at the Río Hondo dam. Data from the Colorado (a tributary of the Salí River) and Medina rivers are also analyzed and compared.  相似文献   

Geochemistry of groundwater in the alluvial plain of Tucumán province, Argentina   总被引：3，自引：0，他引：3  

Gabriela M. García  Margarita del V. Hidalgo  Miguel A. Blesa 《Hydrogeology Journal》2001,9(6):597-610

The Salí River hydrogeological basin is one of the most productive artesian basins in Argentina. It is located in the southeastern part of the province of Tucumán, northwestern Argentina, and its groundwater resources are developed for water supply and irrigation. The chemical composition of the water is strongly influenced by the interaction with the basinal sediments and by hydrologic characteristics such as the flow pattern and time of residence. Three hydrochemical zones are defined in the study area and the processes that control the chemical composition of the water are manifestly different in each zone. The dissolution of halite, sodium sulphate, and gypsum explains part of the contained Na⁺, K⁺, Cl^–, SO₄ ^2–, and Ca²⁺, but other processes, such as cation exchange, calcite precipitation, weathering of aluminosilicates, and gas exchange with the atmosphere, also contribute to the water composition. The assessment of contamination indicators, such as pH, dissolved organic matter, dissolved oxygen, phosphate, and nitrate, indicates that the groundwater is suitable for human consumption. However, biological contamination has been detected in samples from some wells, especially those near the Salí River. Electronic Publication  相似文献   

Quantification of salt weathering in porous stones using an experimental continuous partial immersion method   总被引：1，自引：0，他引：1  

D. Benavente  M. A. Garcí  a del Cura  A. Bernab  u  S. Ord    ez 《Engineering Geology》2001,59(3-4):313-325

In this study, an experimental salt weathering simulation and porous stone durability classification are proposed. There are many laboratory tests that quantify durability against salt crystallisation weathering action. These are usually based on the total immersion of samples into a saline solution, which is not representative of the salt weathering mechanism. An experimental test based on partial immersion is suggested. This is a comparable study of weight loss and degradation of visual appearance due to salt crystallisation using, on the one hand, a standard durability test (UNE), and, on the other, the proposed durability test. The weight loss and visual appearance in our test is comparable to the degradation of building stone. The differences between weight loss data in both tests depend on the petrophysical properties: porous media and degree of coherence.

From this testing, a new durability classification as a function of dry weight loss in the partial immersion test is proposed. Four divisions of different types of materials can be made in this classification, which quantifies salt weathering action mainly in environments and mild climatic conditions.  相似文献   

Thermochronology and exhumation rates of granitic intrusions at Mesa Central,Mexico     

Angel F. Nieto-Samaniego  María de Jesús Paulina Olmos-Moya  Gilles Levresse  Susana A. Alaniz-Alvarez  Fanis Abdullin  Alexis del Pilar-Martínez 《International Geology Review》2020,62(3):311-319

ABSTRACT

The Mesa Central of Mexico (MC) is an elevated plateau located 2000 m above sea level in central Mexico, where intrusions outcrop that register the history of exhumation-erosion occurring during the Late Cretaceous-Paleogene. The tectonic history of the region records formation of the Late Cretaceous-Paleogene ‘Mexican orogen’; this was followed by extension of the entire region and several plutons were then exhumed. The age and magnitude of the crustal uplift and erosion occurring during exhumation has not been addressed to date. Therefore, this study reports the crystallization and cooling ages of two plutons, the Tesorera Granodiorite and the Comanja Granite, and estimates their emplacement depths. Based on these data, the exhumation age of the Tesorera Granodiorite is estimated to be between ~73 Ma and ~63 Ma at an exhumation rate of ~528 m/m. y. and that of the Comanja Granite is 52 Ma and 48 Ma at an exhumation rate of ~2500 m/m. y. Exhumation-erosion event of the Tesorera Granodiorite was located on the trace of the San Luis-Tepehuanes Fault System and that of the Comanja Granite on the a trace of the El Bajío Fault System. Furthermore, the high exhumation rate in the Comanja Granite suggests that gravitational collapse played an important role during exhumation.  相似文献   

Supernova 1994aj: a probe for pre-supernova evolution and mass-loss from the progenitor     

S. Benetti  E. Cappellaro  I. J. Danziger  M. Turatto  F. Patat  & M. Della Valle 《Monthly notices of the Royal Astronomical Society》1998,294(3):448-456

Extensive photometric and spectroscopic observations of SN 1994aj until 540 d after maximum light have been obtained. The photometry around maximum suggests that the SN belongs to the Type II Linear class, with a peak absolute magnitude of M _V∼−17.8 (assuming H ₀=75 km s⁻¹ Mpc⁻¹). The spectra of SN 1994aj were unusual, with the presence of a narrow line with a P Cygni profile on top of the broad Balmer line emission. This narrow feature is attributed to the presence of a dense superwind surrounding the SN. At 100–120 d after maximum light the SN ejecta start to interact with this circumstellar material. The SN luminosity decline rates slowed down [γ _R =0.46 mag (100 d)⁻¹], becoming less steep than the average late luminosity decline of normal SN II [∼1 mag (100 d)⁻¹]. This dense ( ˙M / u _W∼10¹⁵ g cm⁻¹) wind was confined to a short distance from the progenitor ( R _out=∼5×10¹⁶ cm), and results from a very strong mass-loss episode ( ˙M =10⁻³ M⊙ yr⁻¹), which terminated shortly before explosion (∼5–10 yr).  相似文献   

Velocity of auroral arcs drifting equatorward from the polar cap     

P. J. S. Williams  C. F. del Pozo  I. Hiscock  R. Fallows 《Annales Geophysicae》1998,16(10):1322-1331

The drift velocity of an auroral arc is compared with the component of F-region plasma velocity in the same direction for ten cases where the arc is seen to move steadily equatorward for several minutes without any major change in appearance or orientation. In most cases the two velocities are close, but on two occasions the drift velocity of the arc is much higher than the plasma velocity. From the cases studied it appears that during the growth and recovery phase of the substorm cycle the arc moves with a velocity close to the convection velocity, but during the expansion phase this is not the case.  相似文献   

Carbonatation processes at the El Berrocal natural analogue granitic system (Spain): inferences from mineralogical and stable isotope studies     

E. Reyes  L. Prez del Villar  A. Delgado  G. Cortecci  R. Núez  M. Pelayo  J. S. Czar 《Chemical Geology》1998,150(3-4):293-315

The El Berrocal granite/U-bearing quartz vein system has been studied as a natural analogue of a high-level radioactive waste repository. The main objective is to understand the geochemical behaviour of natural radionuclides occurring under natural conditions. In this framework, the carbonatation processes have been studied from a mineralogical and isotopic ( and ) point of view, since carbonate anions are powerful complexing agents for U(VI) under both low-temperature hydrothermal and environmental conditions. The carbonatation processes in the system are identified by the presence of secondary ankerite, with minor calcite, scattered in the hydrothermally altered granite, and Mn calcite in fracture filling materials. The isotopic signatures of these carbonates lead us to conclude that ankerite and calcite from the former were formed at the end of the same hydrothermal process that altered the granite, at a temperature range of between 72° and 61°C for ankerite, and between 52° and 35°C for calcite. The effect of edaphic CO₂ on both carbonates, greater on calcite than on ankerite, is demonstrated. Calcites from fracture fillings are, at least, binary mixtures, in different proportions, of hydrothermal calcite, formed between 25° and <100°C, and supergenic calcite, formed at ≤25°C. According to their signatures, the effect of edaphic CO₂ in both calcites is also evident. It is assumed that: (i) hydrothermal calcite from fracture fillings and ankerite from the hydrothermally altered granite are the result of the same hydrothermal process, their chemical differences being due to the intensity of the water/rock interaction which was stronger in the altered granite than in the fractures; and (ii) all of these carbonatation processes are responsible for ancient and recent migration/retention of uranium observed in the hydrothermally altered granite and fracture fillings.  相似文献   

Deviations from Classical Behaviour in Pumping Test Analysis     

Maria del  Mar Gonzalez K. R. Rushton 《Ground water》1981,19(5):510-516

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